论文标题

磁性表面上的对映选择性吸附

Enantioselective adsorption on magnetic surfaces

论文作者

Safari, Mohammad Reza, Matthes, Frank, Caciuc, Vasile, Atodiresei, Nicolae, Schneider, Claus M., Ernst, Karl-Heinz, Bürgler, Daniel E.

论文摘要

从分子理论的开头,手性和磁性的相互作用引起了科学家的兴趣。仍然存在一个问题,是否在磁性表面上发生手性分子的对映体吸附。对映异构体的歧视是由手性诱导的分子内的自旋分离引起的,并与基材的磁化相互作用。在这里,我们表明,单个螺旋芳族烃会在铁磁钴表面上进行对映选择性吸附。自旋和手性敏感的扫描隧道显微镜表明,相反的分子更喜欢吸附在平面外磁化的钴岛上。随着最终化学吸附状态的迁移率停止,得出的结论是,对映选择必须发生在物理的瞬态前体状态。最新的自旋分辨Ab从头算模拟通过反驳对映体依赖性化学吸附能来支持这种情况。这些发现表明,范德华的相互作用还应包括对分子磁磁体过程至关重要的自旋 - 丝离素。

From the beginning of molecular theory, the interplay of chirality and magnetism has intrigued scientists. There is still the question if enantiospecific adsorption of chiral molecules occurs on magnetic surfaces. Enantiomer discrimination was conjectured to arise from chirality-induced spin separation within the molecules and exchange interaction with the substrate's magnetization. Here we show that single helical aromatic hydrocarbons undergo enantioselective adsorption on ferromagnetic cobalt surfaces. Spin and chirality sensitive scanning tunneling microscopy reveals that molecules of opposite handedness prefer adsorption onto cobalt islands with opposite out-of-plane magnetization. As mobility ceases in the final chemisorbed state, it is concluded that enantioselection must occur in a physisorbed transient precursor state. State-of-the-art spin-resolved ab initio simulations support this scenario by refuting enantio-dependent chemisorption energies. These findings demonstrate that van der Waals interaction should also include spin-fluctuations which are crucial for molecular magnetochiral processes.

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