论文标题
具有调制表面电荷密度的电动双层:精确的2D结果
Electric double layers with modulated surface charge density: Exact 2D results
论文作者
论文摘要
仅带有柜台的电动双层(EDL),例如具有基本电荷$ -e $的电子在反温度$β$下的热平衡。特别是,我们研究了表面电荷调制对颗粒数密度曲线和压力的影响。移动颗粒被约束至2D缸的表面,并浸入真空中(无介电图像电荷)。 EDL对应于载有(固定)位置依赖性线电荷密度的圆柱的末端。考虑了一个单个EDL的几何形状和距离$ D $的两个EDL;研究了两个几何形状的粒子密度曲线,两个EDL的有效相互作用由两个线壁上的颗粒压力给出。对于任何耦合常数$γ\equivβe^2 = 2 \ times {\ rm Integer} $,存在将2D一组分库仑系统的映射到定义在站点链上的一维相互作用的抗势场理论上。使用抗强制变量的特定变换对称性,将接触值定理推广到具有调制线电荷密度的EDL。对于自由屈服耦合$γ= 2 $,表明在某些条件下,抗强制变量之间的相互作用强度对角度化的矩阵将其对角度化,从而允许一个人获得粒子密度谱以及压力的精确公式。获得的结果证实了先前的弱耦合和蒙特卡洛观察的迹象,即表面电荷不均匀性意味着与带电线接触时的反子密度增强,并且与均匀带电的均匀线相比,两条平行线之间的压力减小(具有相同的平均电荷荷矿物质)。
Electric double layers (EDL) with counterions only, say electrons with the elementary charge $-e$, in thermal equilibrium at the inverse temperature $β$ are considered. In particular, we study the effect of the surface charge modulation on the particle number density profile and the pressure. The mobile particles are constrained to the surface of a 2D cylinder and immersed in vacuum (no dielectric image charges). An EDL corresponds to the end-circle of the cylinder which carries a (fixed) position-dependent line charge density. The geometries of one single EDL and two EDLs at distance $d$ are considered; the particle density profile is studied for both geometries, the effective interaction of two EDLs is given by the particle pressure on either of the line walls. For any coupling constant $Γ\equiv βe^2 = 2\times {\rm integer}$, there exists a mapping of the 2D one-component Coulomb system onto the 1D interacting anticommuting-field theory defined on a chain of sites. Using specific transformation symmetries of anticommuting variables, the contact value theorem is generalized to the EDL with modulated line charge density. For the free-fermion coupling $Γ=2$ it is shown that, under certain conditions, the matrix of interaction strengths between anticommuting variables diagonalizes itself which permits one to obtain exact formulas for the particle density profile as well as the pressure. The obtained results confirm the previous indications of weak-coupling and Monte Carlo observations that the surface charge inhomogeneity implies an enhancement of the counterion density at the contact with the charged line and a diminution of the pressure between two parallel lines in comparison with the uniformly charged ones (with the same mean charge densities).